期刊
ORGANIC LETTERS
卷 17, 期 2, 页码 254-257出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503338b
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资金
- Deutsche Forschungsgemeinschaft (IRTG Munster/Nagoya)
Readily prepared N-aminopyridinium salts are valuable precursors for the generation of N-centered radicals. Reduction of these salts by single electron transfer allows for clean generation of amidyl radicals. It is shown that direct radical CH amination of heteroarenes and arenes can be achieved with N-aminopyridinium salts under mild conditions by using photoredox catalysis.
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