期刊
ORGANIC LETTERS
卷 16, 期 6, 页码 1772-1775出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5004725
关键词
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资金
- Marie Curie ITN MEMTIDE [FP7-PEOPLE-ITN08]
- CICYT [CTQ2012-30930]
- Generalitat de Catalunya [2009SGR 1024]
Contrary to other studies, here we describe cysteine (Cys) pseudoproline-containing peptides with short deprotection times in TFA. The deprotection times fell in the same range as other protecting groups commonly used in SPPS (e.g., 1-3 h). Moreover, when using Cys pseudoprolines as peptide macrocyclization-enhancing moieties a considerable reduction in reaction time was observed compared to a peptide containing trityl protected Cys.
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