期刊
ORGANIC LETTERS
卷 16, 期 11, 页码 2908-2911出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501048x
关键词
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资金
- CSIR
- CSIR-Network project [BSC0102]
- DST [CS-399/2012]
A novel palladium-catalyzed approach to 2-benzofuranyl/indolylacetamides from 1-(o-hydroxy/aminophenyl)propargylic alcohols and isocyanides is described. The reaction proceeds through a cascade that includes oxy/aminopalladation, isocyanide insertion, and 1,4-hydroxyl migration. No oxidant or ligand is needed to promote the cascade, and the reactions are carried out under mild conditions to afford the products through high functional tolerance.
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