期刊
ORGANIC LETTERS
卷 16, 期 17, 页码 4642-4645出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502237a
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-
资金
- Ministry of Science and Technology of Republic of China [MOST 103-2113-M-032-009-MY2]
A novel procedure for the cascade reaction of the addition of a Grignard reagent to a nitrile with a copper-catalyzed C-N bond coupling was developed, which afforded various polysubstituted phenanthridines in moderate to good yields with tolerance for a wide variety of substrates. Experimental data demonstrated that the reaction proceeded more likely through a Cu(I/III) catalytic cycle.
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