期刊
ORGANIC LETTERS
卷 16, 期 7, 页码 2058-2061出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500662f
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-
资金
- National Basic Research Program of China [2011CB808706]
- National Natural Science Foundation of China [21232006, 21272249]
- Chinese Academy of Sciences
A highly efficient, redox-free Pd(II)-catalyzed tandem cyclization reaction initiated by intramolecular amino-palladation of alkynes followed by nucleophilic addition to nitrites is developed. This method provides a versatile approach for the synthesis of six- to eight-membered ring-fused indoles in one step and has also shown advantages in the formal synthesis of (+/-)-aspidospermidine.
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