期刊
ORGANIC LETTERS
卷 16, 期 15, 页码 3896-3899出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501574f
关键词
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资金
- National Natural Science Foundation [NSF 21272101, 201302076]
- National Basic Research Program of China (973 Program) [2010CB8-33203]
- Fundamental Research Funds for the Central Universities [lzujbky-2014-243, lzujhky-2014-194]
- 111 Project
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1138]
A novel three-component strategy for the cyanotrifluoromethylation/azidotrifluoromethylation and carbocyclization of 1,6-enynes is developed. The reaction proceeds smoothly under a moderate temperature by using a copper catalyst, which provides a rapid and concise access to addition-carbocyclization products. Furthermore, the products obtained can be useful building blocks in discoveries of lead compounds and other biologically active CF3-containing heterocycles.
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