期刊
ORGANIC LETTERS
卷 16, 期 21, 页码 5616-5619出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502397f
关键词
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资金
- National Natural Science Foundation [NSF 21272101, 201302076]
- National Basic Research Program of China (973 Program) [2010CB8-33203]
- Fundamental Research Funds for the Central Universities [lzujbky-2014-194, lzujbky-2014-243]
- 111 Project
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1138]
A silver-promoted oxidative cyclization of 1,6-enynes with disubstituted phosphine oxides is developed for the synthesis of fluorene derivatives. The reaction proceeds with high regioselectivity by constructing one C-P bond and two C-C bonds in one step. Moreover, reduction of the pentavalent phosphine enlarges the application scope of the product.
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