期刊
ORGANIC LETTERS
卷 16, 期 15, 页码 3962-3965出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501770q
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资金
- National Natural Science Foundation of China [21325209]
- Shanghai Municipal Committee of Science and Technology [14XD1404400]
A highly enantioselective rhodium-catalyzed arylation of cyclic diketimines with arylboronic acids was achieved under mild conditions by employing a simple, sulfmamide-based branched olefin ligand. This protocol provides an efficient access to valuable chiral tetrasubstituted 1,2,5-thiadiazoline 1,1-dioxides in high yields with excellent enantioselectivities of up to 99% ee.
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