期刊
ORGANIC LETTERS
卷 16, 期 24, 页码 6424-6427出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503246k
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资金
- Department of Science and Technology (DST)
- Council of Scientific and Industrial Research (CSIR), New Delhi
- CSIR, New Delhi
An oxygen substituted donoracceptor cyclopropane (DAC) is used as a common intermediate in the enantiospecific collective total synthesis of butanolide- and butenolide-based natural products like (+)-juruenolide C and D, (+)-blastmycinone, (+)-antimycinone, and (+)-ancepsenolide. Enantiospecific first total syntheses of (+)-hydroxyancepsenolide and its acetate are achieved confirming their absolute stereochemistry.
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