期刊
ORGANIC LETTERS
卷 16, 期 22, 页码 5827-5829出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5029157
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-
资金
- Cytec Canada, Inc.
- Natural Sciences and Engineering Research Council (NSERC)
A simple, efficient, and regioselective synthesis of 3-methyl-3,4-dihydrocoumarins is reported. The reaction of 2-allyl phenols with synthesis gas was catalyzed by PdI2, and 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane (L1) and 1,3,5,7-tetramethyl-6-tetradecyl-2,4,8-trioxa-6-phosphaadamantane (L2) were effective as ligands, affording good product selectivity in all cases.
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