期刊
ORGANIC LETTERS
卷 16, 期 21, 页码 5636-5639出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502708z
关键词
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资金
- NIGMS [R01 GM-081376]
- Eli Lilly
One major synthetic route to the synthesis of benzyl amines, ethers, and esters is the nucleophilic substitution of a benzylic halide. To develop a method for the facile synthesis and functionalization of the isosteric azaborines, 2-chloromethyl-2,1-borazaronaphthalene has been synthesized in one step to afford a similar common precursor to a benzylic halide. This BN isostere has been shown to be an effective building block by serving as an electrophile in substitution reactions with a large variety of nucleophiles.
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