期刊
ORGANIC LETTERS
卷 16, 期 23, 页码 6052-6055出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503046u
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资金
- Natural Science Foundation of China (NSFC) [31270403]
- NSFC-Shandong Joint Fund for Marine Science Research Centers [U1406402]
- Ministry of Science and Technology of China [2010CB833802, 2013AA092901]
Penicibilaenes A (1) and B (2), two sesquiterpenes possessing a tricyclo[6.3.1.0(1,5)]dodecane skeleton, were characterized from Penicillium bilaiae MA-267, a fungus obtained from the rhizospheric soil of the mangrove plant Lumnitzera racemosa. The lack of some key COSY and NOESY correlations made the structure elucidation of compound 1 difficult, which was solved by a X-ray crystallographic study. Compounds 1 and 2 exhibited selective activity against the plant pathogenic fungus Colletotrichum gloeosporioides (MIC = 1.0 and 0.125 mu g/mL, respectively).
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