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卷 16, 期 23, 页码 6148-6151出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503011g
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- DST, New Delhi [SR/S1/OC-17/2011]
- CSIR [CSC0405]
- UGC
- CSIR
A total synthesis of Deoxy-solomonamide B was accomplished starting from tryptophan in an efficient manner by mimicking the proposed biogenetic route. The present synthesis utilizes a crotylation, oxidative cleavage of the indole moiety, and macrolactamization as key steps. The use of the indole nucleus as a masked anthranilic acid unit paves the way for the easy synthesis of related macrocycles and natural products where the ortho-acyl aniline moiety is embedded into them, which otherwise is difficult to synthesize.
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