期刊
ORGANIC LETTERS
卷 16, 期 19, 页码 5108-5111出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502431b
关键词
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资金
- Natural Science Foundation of China [21172162, 21372174]
- Young National Natural Science Foundation of China [21202111]
- Ph.D. Programs Foundation of Ministry of Education of China [2013201130004]
- Young Natural Science Foundation of Jiangsu Province [BK2012174]
- PAPD
- Soochow University
An efficient I-2 (20 mol %)/TBPB mediated oxidative formal [4 + 1] cycloaddition of N-tosylhydrazones with anilines via C-N/N-N bond formation and S-N cleavage has been developed. This protocol represents a simple, general, and efficient approach for the construction of 1,2,3-triazoles under metal-free and azide-free conditions by utilizing a catalytic amount of I-2.
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