期刊
ORGANIC LETTERS
卷 16, 期 9, 页码 2458-2461出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5008422
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-
资金
- National Institute of General Medical Sciences [GM60567]
A dianionic Ireland-Claisen rearrangement of chiral, nonracemic alpha-methyl-beta-hydroxy allylic esters has been developed that proceeds with high diastereoselectivity and provides products containing three contiguous stereogenic carbons, including a quaternary center. The potential utility of the rearrangement for complex molecule synthesis is also demonstrated.
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