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ORGANIC LETTERS
卷 16, 期 4, 页码 1068-1071出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403602j
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资金
- National Science Council of Taiwan [NSC-102-2119-M-002-007]
- National Taiwan University [NTU-102-R890913]
Threading of di-, tri-, and tetra(ethylene glycol) through the macrocycle BPX26C6 in the presence of templating Na+ ions was proven by the synthesis of the corresponding [2]rotaxanes under solvent-free conditions. Among them, a [2]rotaxane featuring both tetra(ethylene glycol) and carbamate stations behaves as a molecular switch that can be controlled reversibly through the application of the KTFPB/[2.2.2]cryptand reagent pair.
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