期刊
ORGANIC LETTERS
卷 16, 期 13, 页码 3576-3579出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501579d
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资金
- CSIR-New Delhi [ORIGIN-CSC0108]
- CSIR-New Delhi
The reaction of arynes with indene/benzofurans has been developed. The arynes were generated from 2(trimethylsilyl)aryl triflates by the fluoride-induced 1,2-elimination react with indene or various benzofurans proceeding via a cascade reaction involving the Diels-Alder reaction and a [2 + 2] cycloaddition reaction. The tandem process afforded functionalized dihydrobenzocyclobutaphenanthrenes in moderate to good yields. Moreover, the method has been utilized for the one-pot synthesis of benzo[b]fluoranthene.
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