期刊
ORGANIC LETTERS
卷 16, 期 24, 页码 6504-6507出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol503410e
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资金
- University of Virginia
The first ketone-catalyzed method for the oxidation of aliphatic C-H bonds is reported. The reaction conditions employ aryl trifluoromethyl ketones in catalytic amounts and hydrogen peroxide as the terminal oxidant. Hydroxylation is stereospecific and chemoselective for tertiary over secondary C-H bonds. A catalytic cycle invoking a dioxirane as the active oxidant is proposed.
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