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卷 16, 期 17, 页码 4392-4395出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501766m
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- CSIR, New Delhi
A novel tandem oxidative conversion of 10,11-dihydro-5H-dibenzo[b,e][1,4]diazepines to phenazines has been achieved under transition-metal-free, mild conditions using K2S2O8 or DDQ as the oxidizing agent. The transformation proceeds through oxidative removal of a benzylic methylene group by C-C and C-N bond cleavage followed by a new aryl C-N bond formation under radical conditions.
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