期刊
ORGANIC LETTERS
卷 16, 期 5, 页码 1402-1405出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500173y
关键词
-
资金
- National Science Foundation [CBET-0854105]
- GAANN Fellowship [P200A120213-13]
A new method for determination of absolute configuration (AC) is demonstrated using an enantiomeric pair of molecularly imprinted polymers, referred to as DuoMIPs. The ratio of HPLC capacity factors (k') for the analyte on each of the DuoMIPs is defined as the gamma factor and can be used to determine AC when above 1.2. A mnemonic based on the complementary binding geometry of the DuoMIPs was used to aid in understanding and prediction of AC.
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