期刊
ORGANIC LETTERS
卷 16, 期 3, 页码 816-819出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403557q
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资金
- National Natural Science Foundation of China [21332009]
- Specialized Research Fund for the Doctoral Program of Higher Education [20120071110009]
- Shanghai Science and Technology Committee [12ZR1425600]
A facile approach to construct 3,4-fused tricyclic azepino[5,4,3-cd]indoles from 2-alkynyl anilines, isocyanides, and alpha,beta-unsaturated acids is reported. This synthetic process involves a regioselective meta-functionalization of 2-alkynylanilines using a dearomatization strategy and a palladium(II)-catalyzed domino heterocyclization/Heck reaction.
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