期刊
ORGANIC LETTERS
卷 16, 期 14, 页码 3804-3807出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501693j
关键词
-
资金
- National Science Foundation [CHE 1153003]
A combined inter-/intramolecular oxidative diamination of terminal alkenes is described that uses a hypervalent iodine oxidant and a nucleophilic amine to produce 3-aminoindolines at room temperature. This operationally straightforward and metal-free protocol is compatible with a broad range of functional groups. A mechanism involving the conversion of the amine to an electrophilic nitrogen source is advanced and used to identify a protocol effective with substoichiometric amounts of iodide and commercially available phenyl iodobenzene diacetate (PIDA) as the stoichiometric oxidant.
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