期刊
ORGANIC LETTERS
卷 16, 期 2, 页码 568-571出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403441c
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资金
- Deutsche Forschungsgemeinschaft [Ki 379/16-1]
- Fonds der Chemischen Industrie
The antibiotic elansolid B1 was prepared by a convergent strategy that relied on a highly diastereoselective, biomimetic intramolecular Diels-Alder cycloaddition (IMDA) that furnished the tetrahydroindane unit. Other key features are a double Sonogashira cross-coupling and a substrate-controlled Yamamoto aldol reaction.
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