期刊
ORGANIC LETTERS
卷 16, 期 3, 页码 984-987出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403709g
关键词
-
资金
- NSFC [21172150, 21321061, 21290180]
- NBRPC (973 Program) [2010CB833200]
- NCET [12SCU-NCET-12-03]
- Sichuan University
An intramolecular [1,4]-S- to O-silyl migration has been used to form silyl enol ethers with Z-configurational control. The silyl migration also creates a new anion center at sulfur, which can subsequently react with electrophiles to generate Z-silyl enol ethers with diverse thioether linkages. The synthetic utility of this pathway was demonstrated by modifying the Z-silyl enol ethers with aldehydes via a Mukaiyama aldol reaction or Prins cyclization to generate functionalized organosulfur compounds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据