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卷 16, 期 3, 页码 824-827出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403570z
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资金
- Boehringer Ingelheim
- DuPont
- Eli Lilly
- Amgen
- AstraZeneca
- Roche
- Bristol-Myers Squibb
- Camille and Henry Dreyfus Foundation
- A. P. Sloan Foundation
- S. T. Li Foundation
- University of California, Los Angeles
- Foote Family
- UCLA Graduate Division
- NSF [CHE-1048804]
- National Center for Research Resources [S10RR025631]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation
A simple method for the preparation of aryl methyl ketones is reported. The transformation involves the Pd-catalyzed coupling of an acyl anion equivalent, acetyltrimethylsilane, with aryl bromides to afford the corresponding acetylated arenes in synthetically useful yields. The methodology is tolerant of heterocycles and provides a new method for arene functionalization.
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