期刊
ORGANIC LETTERS
卷 16, 期 9, 页码 2394-2397出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5007423
关键词
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资金
- NSFC [91213302, 21272102, 21202071]
- National S&T Major Project of China [2012ZX09S04001-003]
The catalytic asymmetric amination reaction of 3-bromooxindoles with indolines for the construction of the N1-C3 linkage stereogenic centers has been realized for the first time. Moreover, the racemic substrates (3-substituted indolines) were also applicable under the same chiral conditions. The newly developed method conveniently led to a formal synthesis of (+)-psychotrimine.
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