期刊
ORGANIC LETTERS
卷 16, 期 11, 页码 3012-3015出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501135p
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资金
- Japan Society for the Promotion of Science [23550179]
- Grants-in-Aid for Scientific Research [23550179, 26288087] Funding Source: KAKEN
Ru(II)-Pheox-catalyzed asymmetric cyclopropanation of diethyl diazomethylphosphonate with alkenes, including alpha,beta-unsaturated carbonyl compounds, afforded the corresponding optically active cyclopropylphosphonates in high yields and with excellent diastereoselectivity (up to 99:1) and enantioselectivity (up to 99% ee).
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