期刊
ORGANIC LETTERS
卷 16, 期 17, 页码 4532-4535出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol502073t
关键词
-
资金
- Russian Foundation for Basic Research (RFBR grant) [14-03-31871]
A novel photochemical rearrangement of diarylethenes bearing oxazole and benzene derivatives as aryl moieties that results in the formation of polyaromatic systems was investigated. The mechanism of the transformation includes photocyclization, sequential [1,9] and [1,3]-hydrogen shifts, as well as a lateral oxazole ring-opening process. It was shown that this reaction can be an effective synthetically preparative method for the preparation of naphthalene (polyaromatic) derivatives.
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