期刊
ORGANIC LETTERS
卷 16, 期 14, 页码 3736-3739出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5015587
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资金
- The Villum Foundation
- Sino-Danish Centre for Education and Research (SDC)
Stable bis(gold(I) alkynyl) complexes of tetraethynylethene (TEE) derivatives were readily prepared and employed in Sonogashira-like palladium-catalyzed phosphine-gold(I) halide elimination reactions with aryl iodides and redox-active tetrathiafulvalene (TTF) mono- and bisiodides. This presents a particularly convenient method for the preparation of symmetrical and asymmetrical tetrathiafulvalene (TTF)-fused radiaannulenes in good yields.
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