期刊
ORGANIC LETTERS
卷 16, 期 12, 页码 3392-3395出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501449j
关键词
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资金
- Singapore National Research Foundation [NRF-RF2009-05]
- Nanyang Technological University
- JST, CREST
A cobalt-diphosphine catalyst promotes the addition of an arylzinc reagent to a norbornene derivative to I afford o-(2-exo-norbornyl)arylzinc species. This migratory arylzincation reaction is considered to involve insertion of norbornene into an arylcobalt species, alkyl-to-aryl 1,4-cobalt migration, and transmetalation between the resulting o-(2-exo-norbornyl)arylcobalt species and the arylzinc reagent. The o-(2-exo-norbornyl)arylzinc species can be intercepted by common organic electrophiles under copper or palladium catalysis.
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