4.8 Article

Nickel-Catalyzed Reaction of Thioisatins and Alkynes: A Facile Synthesis of Thiochromones

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ORGANIC LETTERS
卷 16, 期 21, 页码 5660-5662

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AMER CHEMICAL SOC
DOI: 10.1021/ol5026102

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  1. JST
  2. ACT-C
  3. Ministry of Education, Culture, Sports, Science and Technology, Japan
  4. Japan Society for the Promotion of Science
  5. Grants-in-Aid for Scientific Research [25105729, 23350017] Funding Source: KAKEN

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A new synthetic method for thiochromones was developed by using nickel-catalyzed decarbonylative cycloaddition of readily available thioisatins with alkynes. This reaction proceeded under very mild conditions and has quite high functional group compatibility.

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