期刊
ORGANIC LETTERS
卷 16, 期 2, 页码 504-507出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403391v
关键词
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资金
- National Natural Science Foundation of China [21302088, 21302087]
- Shenzhen special funds for the development of biomedicine, Internet, new energy, and new material industries [JCYJ20130401144532131, JCYJ20130401144532137]
- South University of Science and Technology of China
The first example of a metal-free direct carbotrifluoromethylation of alkenes using inexpensive TMSCF3 as the CF3 source is described. The methodology not only exhibits high chemoselectivity for this transformation but also expands the substrate scope that is difficult to access by known transition-metal-catalyzed methods.
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