期刊
ORGANIC LETTERS
卷 15, 期 17, 页码 4358-4361出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401858k
关键词
-
资金
- NIH-NIGMS [R01GM101389-01]
- Amgen Young Investigator Award
Redox-neutral formation of C-P bonds in the alpha-position of amines was achieved via a process that features a combination of an oxidative alpha-C-H bond functionalization and a reductive N-alkylation. Benzoic acid functions as an efficient catalyst in this three-component reaction of cyclic secondary amines, aldehydes and phosphine oxides to provide rapid access to alpha-amino phosphine oxides not easily accessible by classic Kabachnik-Fields reactions.
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