期刊
ORGANIC LETTERS
卷 15, 期 24, 页码 6286-6289出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403147v
关键词
-
资金
- program Sustainable Chemical Synthesis (SusChemSys)
- European Regional Development Fund (ERDF)
- state of North Rhine-Westphalia, Germany under the Operational Program Regional Competitiveness and Employment
Readily accessible 2-isocyanobiphenyls react with aromatic aldehydes via base promoted homolytic aromatic substitution (BHAS) to give 6-aroylated phenanthridines. Reactions occur via addition of acyl radicals to the isonitrile functionality and subsequent intramolecular BHAS of the intermediate imidoyl radicals. Initiation of the radical chain reaction is best achieved with small amounts of FeCl3 (0.4 mol %), and the commercially available and cheap fBuOOH is used as the oxidant.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据