4.8 Article

Benzoselenadiazole Fluorescent Probes - Near-IR Optical and Ratiometric Fluorescence Sensor for Fluoride Ion

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ORGANIC LETTERS
卷 16, 期 2, 页码 354-357

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AMER CHEMICAL SOC
DOI: 10.1021/ol403082p

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  1. National Science Council of Taiwan, Republic of China [NSC 102-2113-M-002-003-MY3]
  2. suprainstitutional project STRAIT of CSIR-CLRI

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A highly selective and sensitive near-IR optical sensor, benzoselenadiazole based diarylamine (TBS-HN), for fluoride (F-) has been designed and synthesized. TBS-HN also shows turn-on ratiometric fluorescence signaling in the presence of F- by inhibiting the excited state intramolecular proton transfer (ESIPT) processes.

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