期刊
ORGANIC LETTERS
卷 15, 期 11, 页码 2858-2861出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401185t
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资金
- Landesgraduiertenstiftung Baden-Wurttemberg
- Deutsche Forschungsgemeinschaft [SFB 706]
The chemoselective reduction of alkyne, ketones, or nitro groups using (Ph3P)(3)RuCl2 as an inexpensive catalyst and Zn/water as a stoichiometric reductant is reported. Depending on the nature of the additive and the temperature, good chemoselectivities were observed allowing, e.g., for the selective reduction of a nitro group in the presence of a ketone or an alkyne.
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