期刊
ORGANIC LETTERS
卷 15, 期 5, 页码 1092-1095出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4001153
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资金
- IISc
- RL Fine Chem
- CSIR
A versatile aerobic catalytic system (I-2 and O-2/TBHP) for C-H functionalization is reported. This CDC (cross-dehydrogentive coupling) reaction is compatible with a large number of nucleophiles and is performed under ambient reaction conditions. The scope of the metal-free CDC is illustrated by synthesizing a variety of functionalized tetrahydroisoquinolines and N,N-dimethylaniline. The highlight of the method is a Friedel-Crafts reaction of phenols and indole with tertiary amines.
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