Tetrahydroquinolines and Benzazepines through Catalytic Diastereoselective Formal [4+2]-Cycloaddition Reactions between Donor-Acceptor Cyclopropenes and Imines

Regio- and diastereoselective Lewis acid catalyzed cycloaddition reactions between imines and donor-acceptor cyclopropenes generated from silyl-protected enoldiazoacetates provide direct access to stable cyclopropane-fused tetrahydroquinolines and, with cyclopropane ring opening under mild conditions, to 1H-benzazipine derivatives.