4.8 Article

Access to Indenones by Rhodium(III)-Catalyzed C-H Annulation of Arylnitrones with Internal Alkynes

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ORGANIC LETTERS
卷 15, 期 21, 页码 5440-5443

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AMER CHEMICAL SOC
DOI: 10.1021/ol4025309

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  1. NSFC [21272231]
  2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences

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Under redox-neutral conditions, rhodium(III)-catalyzed C-H annulation of N-tert-butyl-alpha-arylnitrones with internal alkynes has been realized for the synthesis of indenones under mild conditions. This reaction proceeded in moderate to high yields and with good functional group tolerance.

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