期刊
ORGANIC LETTERS
卷 15, 期 7, 页码 1476-1479出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400198q
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资金
- Canada Research Chair Foundation
- CFI
- FQRNT Center for Green Chemistry and Catalysis
- NSERC
- McGill University
- Shaanxi Normal University Program of Training and Studying Abroad for Teachers
A novel rhodium(III)-catalyzed direct functionalization of the ortho-C-H bond of aromatic ketone derivatives and an intramolecular cyclization sequence produced indene derivatives in moderate to good yields. This cascade cyclization involves a conjugate addition of alpha,beta-unsaturated ketone and subsequent aldol condensation. The reaction occurred efficiently in the presence of water and under an atmosphere of air.
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