4.8 Article

An Efficient Approach to the Synthesis of Novel Pyrene-Fused Azaacenes

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ORGANIC LETTERS
卷 15, 期 14, 页码 3594-3597

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AMER CHEMICAL SOC
DOI: 10.1021/ol401438a

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资金

  1. International Collaborative Project Fund of Guizhou province at Guizhou University
  2. Royal Society of Chemistry (RSC)
  3. Grants-in-Aid for Scientific Research [13J01759] Funding Source: KAKEN

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An efficient synthetic approach for functionalization of both the active sites (1,3-) and the K-region (4,5,9,10-) of pyrene was accomplished by bromination and oxidation with considerable yield. These novel pyrene-fused azaacenes were thoroughly investigated by X-ray diffraction studies, electrochemistry, and DFT calculations.

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