期刊
ORGANIC LETTERS
卷 15, 期 11, 页码 2758-2761出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4010917
关键词
-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22106541]
- Grants-in-Aid for Scientific Research [22106541] Funding Source: KAKEN
The first asymmetric total synthesis of (-)-hippodamine has been accomplished via the concise construction of its azaphenalene core, which Is featured by the 2,4,6-chiral piperidine synthesis based on one-pot asymmetric azaelectrocyclization in the partially activated substituent system and the subsequent intramolecular Mannich reaction.
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