期刊
ORGANIC LETTERS
卷 15, 期 13, 页码 3384-3387出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401426p
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资金
- DST-India
- CSIR-India
Nitroolefins are essential elements for both synthetic chemistry and medicinal research. Despite significant improvements in nitration of olefin an efficient metal-free synthesis remains elusive so far. Herein, we disclose a new set of reagents to access nitroolefins in a single step under metal-free conditions. A wide range of olefins with diverse functionalities has been nitrated in synthetically useful yields. This transformation is operationally simple and exhibits excellent E-selectivity. Furthermore, site selective nitration in a complex setup makes this method advantageous.
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