期刊
ORGANIC LETTERS
卷 15, 期 15, 页码 3954-3957出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401735v
关键词
-
资金
- National Science Foundation [CHE 0955972]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0955972] Funding Source: National Science Foundation
An efficient nitration of silyl allenes with nitrogen dioxide radical, generated from NaNO2 and AcOH, to form alpha-nitro-alpha,beta-unsaturated silyl oximes has been developed. A similar nitration could be achieved by using Fe(NO3)(3)center dot 9H(2)O and FeCl3 center dot 6H(2)O, but different from the regioselective oxime formation, two regioisomeric chloride-trapped products were isolated with varying ratios depending on the steric bulk of the silyl group. A novel ring-closure reaction of alpha-nitro-alpha,beta-unsaturated silyl oximes upon treating with TBAF to form isooxazolidinone derivatives was also developed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据