期刊
ORGANIC LETTERS
卷 16, 期 1, 页码 250-253出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403256e
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资金
- Deutsche Forschungs-gemeinschaft (DFG)
A C-P bond and a C-C bond are formed in the synthesis of 6-phosphorylated phenanthridines starting with readily prepared 2-isocyanobiphenyls and commercially available P-radical precursors. The radical cascade reaction comprises addition of an oxidatively generated P-centered radical to the isonitrile functionality and subsequent homolytic aromatic substitution. Various 6-phosphorylated phenanthridines are formed in moderate to excellent yield. In contrast to the currently intensively investigated direct arene phosphorylation, the arene core is constructed with concomitant phosphorylation using this approach.
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