期刊
ORGANIC LETTERS
卷 16, 期 2, 页码 616-619出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403550b
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资金
- Natural Sciences and Engineering Research Council of Canada
- Canada Council for the Arts
Metal-chelation and internal H bonds have been found to greatly enhance the photoelimination quantum efficiency of B,N-heterocycles by 2 orders of magnitude. Green phosphorescent Pt(II)-functionalized 1,2-azaborines have been achieved via photoelimination. A mechanistic pathway for the PE reaction has been established.
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