期刊
ORGANIC LETTERS
卷 15, 期 23, 页码 6038-6041出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402935x
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资金
- project IRAKLEITOS II - University of Crete of the Operational Programme for Education and Lifelong Learning (EPEDVM) of the NSRF
- European Union (European Social Fund)
- National Resources
Supported gold nanoparticles on metal oxides (1 mol %) catalyze for the first time the cis-selective disilylation of terminal alkynes by 1,2-disilanes in isolated yields up to 94%. It is likely that the reaction proceeds through oxidative insertion of the sigma Si-Si bond of disilanes on gold followed by 1,2-addition to the alkyne.
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