期刊
ORGANIC LETTERS
卷 15, 期 12, 页码 2895-2897出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401013s
关键词
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资金
- NIH [GM-43214]
A highly enantioselective addition of phenyl carbamate to meso-epoxides has been developed to efficiently generate protected trans-1,2-amino alcohols. This transformation is promoted by an oligomeric (salen)Co-OTf catalyst and has been used to prepare two useful 2-aminocycloalkanol hydrochlorides in enantiopure form on a multigram scale from commercially available starting materials.
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