期刊
ORGANIC LETTERS
卷 15, 期 15, 页码 3860-3863出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4015915
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-
资金
- European Research Council [25936]
Herein, the regio- and stereoselective iodination, along with some examples for the bromination, of readily available acrylamides to access a variety of differently substituted Z-haloacrylic acid derivatives is reported. The reaction proceeds under mild conditions via a Rh(III)-catalyzed C-H-activation/halogenation mechanism and represents a rare example of a direct halogenation of electron-poor acrylic acid derivatives.
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