期刊
ORGANIC LETTERS
卷 15, 期 10, 页码 2466-2469出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400931p
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资金
- DST, New Delhi
- CSIR
- UGC
Propargyl 1,2-orthoesters of arabinose are exploited for the synthesis of 1,2-trans furanosides; easily accessible 1,2-trans ribofuranosides are converted to challenging 1,2-cis-arabinofuranosides by oxidoreduction. Utility of these protocols was demonstrated by the successful synthesis of major structural motifs present in the cell surface of Mycobacterium tuberculosis. Key furanosylations were carried out under gold-catalyzed glycosidation conditions.
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